Procedure to prepare transparent silica gels

This invention relates to the production of silica gels and in particular to a process for the preparation of silica gels which can be used as a crystal growth medium that simulates the convectionless environment of space to produce structurally perfect crystals. Modern utilizations of substances in electronics, such as radio transmitters and high frequency microphones, often require single crystals with controlled purity and structural perfection. The near convectionless environment of silica gel suppresses nucleation, thereby reducing the competitive nature of crystal growth. This competition limits the size and perfection of the crystal; and it is obviously desirable to suppress nucleation until, ideally, only one crystal grows in a predetermined location. A silica gel is not a completely convectionless environment like outer space, but is the closest known environment to that of outer space that can be created on Earth

The Rasch Sampler

The Rasch sampler is an efficient algorithm to sample binary matrices with given marginal sums. It is a Markov chain Monte Carlo (MCMC) algorithm. The program can handle matrices of up to 1024 rows and 64 columns. A special option allows to sample square matrices with given marginals and fixed main diagonal, a problem prominent in social network analysis. In all cases the stationary distribution is uniform. The user has control on the serial dependency.

Fault detection and location in DC systems from initial di/dt measurement

The use of DC for primary power distribution has the potential to bring significant design, cost and efficiency benefits to a range of power transmission and distribution applications. The use of active converter technologies within these networks is a key enabler for these benefits to be realised, however their integration can lead to exceptionally demanding electrical fault protection requirements, both in terms of speed and fault discrimination. This paper describes a novel fault detection method which exceeds the capability of many current protection methods in order to meet these requirements. The method utilises fundamental characteristics of the converter filter capacitance’s response to electrical system faults to estimate fault location through a measurement of fault path inductance. Crucially, the method has the capability to detect and discriminate fault location within microseconds of the fault occurring, facilitating its rapid removal from the network

Impact of converter interface type on the protection requirements for DC aircraft power systems

The utilization of converter interfaces has the potential to significantly alter the protection system design requirements in future aircraft platforms. However, the impact these converters will have can vary widely, depending on the topology of converter, its filter requirements and its control strategy. This means that the precise impact on the network fault response is often difficult to quantify. Through the analysis of example converter topologies and literature on the protection of DC networks, this paper tackles this problem by identifying key design characteristics of converters which influence their fault response. Using this information, the converters are classified based on their general fault characteristics, enabling potential protection issues and solutions to be readily identified. Finally, the paper discusses the potential for system level design benefits through the optimisation of converter topology and protection system design

Determination of protection system requirements for DC UAV electrical power networks for enhanced capability and survivability

A growing number of designs of future Unmanned Aerial Vehicle (UAV) applications utilise dc for the primary power distribution method. Such systems typically employ large numbers of power electronic converters as interfaces for novel loads and generators. The characteristic behaviour of these systems under electrical fault conditions, and in particular their natural response, can produce particularly demanding protection requirements. Whilst a number of protection methods for multi-terminal dc networks have been proposed in literature, these are not universally applicable and will not meet the specific protection challenges associated with the aerospace domain. Through extensive analysis, this paper seeks to determine the operating requirements of protection systems for compact dc networks proposed for future UAV applications, with particular emphasis on dealing with the issues of capacitive discharge in these compact networks. The capability of existing multi-terminal dc network protection methods and technologies are then assessed against these criteria in order to determine their suitability for UAV applications. Recommendations for best protection practice are then proposed and key inhibiting research challenges are discussed

Preliminary studies in the determination of the volumetric properties of nitrogen using a ballistic piston apparatus

A ballistic piston apparatus is described briefly. The instruments in the apparatus and the associated external measuring circuits are discussed in detail. The differential equations which describe the energy and material transport in the axially-collapsing cylindrical sample-gas chamber are derived and solved numerically. Compressibility factors are calculated for nitrogen gas employing data obtained from two tests made on the ballistic piston apparatus. Temperatures in this investigation range from 2300° to 3300° R, and pressures from 1000 to 6300 pounds per square inch absolute

Optimizing the roles of unit and non-unit protection methods within DC microgrids

The characteristic behavior of physically compact, multiterminal dc networks under electrical fault conditions can produce demanding protection requirements. This represents a significant barrier to more widespread adoption of dc power distribution for microgrid applications. Protection schemes have been proposed within literature for such networks based around the use of non-unit protection methods. This paper shows however that there are severe limitations to the effectiveness of such schemes when employed for more complex microgrid network architectures. Even current differential schemes, which offer a more effective, though costly, protection solution, must be carefully designed to meet the design requirements resulting from the unique fault characteristics of dc microgrids. This paper presents a detailed analysis of dc microgrid behavior under fault conditions, illustrating the challenging protection requirements and demonstrating the shortcomings of non-unit approaches for these applications. Whilst the performance requirements for the effective operation of differential schemes in dc microgrids are shown to be stringent, the authors show how these may be met using COTS technologies. The culmination of this work is the proposal of a flexible protection scheme design framework for dc microgrid applications which enables the required levels of fault discrimination to be achieved whilst minimizing the associated installation costs

A quantum-mechanical perspective on linear response theory within polarizable embedding

The derivation of linear response theory within polarizable embedding is carried out from a rigorous quantum-mechanical treatment of a composite system. Two different subsystem decompositions (symmetric and nonsymmetric) of the linear response function are presented, and the pole structures as well as residues of the individual terms are analyzed and discussed. This theoretical analysis clarifies which form of the response function to use in polarizable embedding, and we highlight complications in separating out subsystem contributions to molecular properties. For example, based on the nonsymmetric decomposition of the complex linear response function, we derive conservation laws for integrated absorption cross sections, providing a solid basis for proper calculations of the intersubsystem intensity borrowing inherent to coupled subsystems and how that can lead to negative subsystem intensities. We finally identify steps and approximations required to achieve the transition from a quantum-mechanical description of the composite system to polarizable embedding with a classical treatment of the environment, thus providing a thorough justification for the descriptions used in polarizable embedding models